2- (4 - Sulfophenylazo) 1,8 - Dihydroxy - 3,6 - Naphthalenedisulfonic Acid, Trisodium Salt
2-%284+-+Sulfophenylazo%291%2C8+-+Dihydroxy+-+3%2C6+-+Naphthalenedisulfonic+Acid%2C+Trisodium+Salt is a chemical substance, according to the current chemical nomenclature, its name is 2- (4-sulfobenzenazo) -1,8-dihydroxy-3,6-naphthalene disulfonate trisodium salt. This substance belongs to the category of organic compounds, containing benzenazo groups, hydroxyl groups and sulfonic acid groups and other functional groups, and is in the state of sodium salt.
In industry, such compounds containing azo structures are often used as dyes. Because of its azo structure, it can absorb light of specific wavelengths, resulting in colorful colors. The introduction of sulfonic acid groups can improve its solubility in water, making it easier to apply to dyeing and finishing processes, and facilitate dyeing operations on fabrics and other materials.
From the perspective of chemical structure, the naphthalene ring is its core structure, which endows the molecule with certain stability and rigidity. The benzenazo group is attached to the naphthalene ring, which greatly affects the electron cloud distribution, which in turn affects its optical properties and makes it have the color characteristics required for dyeing. The presence of hydroxyl groups can participate in a variety of chemical reactions, such as the formation of hydrogen bonds with other compounds, or substitution reactions under specific conditions. The sodium salt form of sulfonic acid groups not only enhances water solubility, but also affects its ionic behavior in solution, such as its surface activity. In conclusion, trisodium 2- (4-sulfonylphenylazo) -1,8-dihydroxy-3,6-naphthalene disulfonate has important applications and research value in dye industry and other fields due to its unique chemical structure.
2- (4 - Sulfophenylazo) 1,8 - Dihydroxy - 3,6 - Naphthalenedisulfonic Acid, What are the main uses of Trisodium Salt
2-% (4-sulfobenzene-azo) 1,8-dihydroxy-3,6-naphthalene disulfonate trisodium salt, which has a wide range of uses. In the dyeing and weaving industry, it is often used as a dye. Due to its unique structure, it can be combined with fabric fibers to make the fabric appear colorful, and has a certain color fastness. After multiple washes and sun exposure, the color is not easy to fade.
In the field of analytical chemistry, it can be used as an analytical reagent. With its characteristics of color reaction with specific metal ions, it can accurately determine the content of metal ions. For example, in water quality testing, qualitative and quantitative analysis of certain trace metal ions can be carried out to help judge the quality of water quality.
It is also an important chemical raw material in the path of scientific research and exploration. Researchers use it to participate in many organic synthesis reactions to prepare new materials with special properties and promote the development of materials science. For example, when developing functional polymer materials, this compound can be used as a key monomer or modifier to give the material unique optical and electrical properties.
It is also indispensable in many aspects of industrial production. In the paper industry, it can be used for paper dyeing to improve the appearance quality of paper; in the leather processing industry, it can be used as a leather dyeing and tanning aid to make leather uniform and better texture.
2- (4 - Sulfophenylazo) 1,8 - Dihydroxy - 3,6 - Naphthalenedisulfonic Acid, Trisodium Salt What are the physicochemical properties
2-%284+-+Sulfophenylazo%291%2C8+-+Dihydroxy+-+3%2C6+-+Naphthalenedisulfonic+Acid%2C+Trisodium+Salt, namely 2- (4-sulfonylphenylazo) -1,8-dihydroxy-3,6-naphthalene disulfonate trisodium salt, this material has unique physical and chemical properties.
Looking at its properties, it is mostly in solid form at room temperature, or in powder form, and the color often shows a specific tone, or yellow, orange and the like, depending on the purity and crystal form. Its solubility is quite characteristic, and it can show a certain solubility in water. Due to the structure of sulfonyl sodium salt, it dissolves by the action of ions and water molecules, but the degree of solubility is affected by temperature, pH, etc. It can be heated or soluble, and the specific pH environment also affects the dissolution balance.
When it comes to stability, the substance can remain stable under conventional conditions. However, in the case of strong oxidizing agents, reducing agents or extreme acid-base environments, azo groups, hydroxyl groups and sulfonic acid groups in the structure may react and cause structural changes. The duration and intensity of illumination also play a role. Azo groups are sensitive to light, and strong light for a long time or luminescent chemical reactions cause color and other properties to change.
From the perspective of spectral properties, due to the conjugated system, there is a characteristic absorption peak in the ultraviolet-visible spectral region. Azo groups are conjugated with naphthalene rings, and the absorption is significant at specific wavelengths. It can be identified and quantified by spectral analysis.
In addition, its ionic behavior in solution cannot be ignored. As a sodium salt, sodium ions and corresponding anions are ionized in water, and the ionic concentration affects the physical properties such as the conductivity of the solution. And the anionic structure contains acidic groups, and there is ionization equilibrium under different pH conditions, which affects the chemical activity and existence form of the substance.
2- (4 - Sulfophenylazo) 1,8 - Dihydroxy - 3,6 - Naphthalenedisulfonic Acid, Trisodium Salt in what industry is widely used
2-%284+-+Sulfophenylazo%291%2C8+-+Dihydroxy+-+3%2C6+-+Naphthalenedisulfonic+Acid%2C+Trisodium+Salt, the Chinese name is often 2- (4-sulfobenzene-azo) -1,8-dihydroxy-3,6-naphthalene disulfonate trisodium salt, which is widely used in printing and dyeing and dye industries.
This compound has an azo structure and a sulfonic acid group, resulting in good water solubility and color characteristics. In the printing and dyeing industry, it is often used as an acid dye. When fabrics are dyed, their sulfonic acid groups are combined with amino groups, hydroxyl groups and other groups on fabric fibers through ionic bonds or hydrogen bonds to achieve fabric coloring. Due to the naphthalene ring and azo group in the structure, it can produce a specific absorption spectrum, showing rich colors, and bright colors and good fastness. It is widely used in textile printing and dyeing for fabric dyeing and printing. Whether it is natural fibers such as cotton, wool, silk, or man-made fibers such as polyester and nylon, it can be applied to give fabrics a variety of colors.
In the dye industry, it is an important intermediate for the synthesis of other complex dyes. Based on its structural characteristics, through a series of chemical reactions, such as nucleophilic substitution, coupling reactions, etc., other functional groups or structural fragments are introduced to expand the types and properties of dyes to meet the special requirements of different industries for dye color fastness, light resistance, and washable resistance. In the process of preparing reactive dyes and direct dyes, it is often used as a starting material to chemically modify new dye molecules to improve the application performance of dyes. In short, this compound plays a significant role in the printing and dyeing and dye industries, providing key support for the development of related industries.
2- (4 - Sulfophenylazo) 1,8 - Dihydroxy - 3,6 - Naphthalenedisulfonic Acid, Trisodium Salt
2-%284+-+Sulfophenylazo%291%2C8+-+Dihydroxy+-+3%2C6+-+Naphthalenedisulfonic+Acid%2C+Trisodium+Salt is 2- (4-sulfobenzene-azo) -1,8-dihydroxy-3,6-naphthalene disulfonic acid trisodium salt, which is often used as a dye intermediate. The preparation method is not detailed in the ancient book "Tiangong Kaiqi", but according to the current chemical understanding, the following steps can be taken.
The starting material is often selected from naphthalene compounds, such as naphthalene. After sulfonation, concentrated sulfuric acid or fuming sulfuric acid is used as a sulfonating agent. At a suitable temperature, such as 160-180 ° C, naphthalene reacts with the sulfonating agent to obtain a mixture of 1,5-naphthalene disulfonic acid and 1,8-naphthalene disulfonic acid and other isomers. After separation, 1,8-naphthalene disulfonic acid can be enriched.
Then, 1,8-naphthalenedisulfonic acid is hydroxylated under specific conditions. Treatment with alkaline substances such as sodium hydroxide, control the reaction temperature and time, and partially convert the sulfonic acid group into a hydroxyl group to obtain 1,8-dihydroxy-3,6-naphthalenedisulfonic acid.
Then take p-aminobenzenesulfonic acid, through the method of diazotization, react with sodium nitrite and hydrochloric acid at low temperature, such as 0-5 ° C, to obtain diazonium salt. This diazonium salt is coupled with 1,8-dihydroxy-3,6-naphthalenedisulfonic acid in a weakly basic medium to obtain 2- (4-sulfobenzene-azo) -1,8-dihydroxy-3,6-naphthalenedisulfonic acid.
Finally, 2- (4-sulfobenzene-azo) -1,8-dihydroxy-3,6-naphthalenedisulfonic acid is neutralized with sodium hydroxide to make the sulfonic acid group into a sodium salt. After concentration, crystallization and drying, the finished product of 2- (4-sulfobenzene-azo) -1,8-dihydroxy-3,6-naphthalenedisulfonic acid trisodium salt can be obtained. Each step of the reaction requires fine temperature control, time control, and material ratio control, and the method of separation and purification is also related to the purity and quality of the product.