What is the chemical structure of 2,7 -di-O- (arsophenylazo) -1,8 -dihydroxynaphthalene-3,6 -disulfonic acid
2% 2C7-di-O- (benzyl carbonyl oxygen) - 1% 2C8-dinaphthyl methyl ether - 3% 2C6-disulfonic acid, its chemical structure is as follows.
In this compound, a di-O- (benzyl carbonyl oxygen) group is connected at the 2,7 position. The benzyl group is benzyl, and its structure is benzene ring-linked methylene (-CH 2O -), and the carbonyl oxygen is the oxygen atom connected to the carbonyl group (C = O). This part of the structure is related to the 2,7 position of the main structure by the oxygen atom.
1,8-dinaphthyl methyl ether moiety, naphthyl group is the remaining group after the naphthalene ring loses one hydrogen atom, two naphthalene groups are connected at positions 1,8 and are connected by methyl ether bonds (-O-CH). The oxygen atom of the methyl ether bond is connected to the naphthalene group at one end, and the other end is connected to the methyl group.
3,6-disulfonic acid moiety, the sulfonic acid group (-SO-H) is connected to the overall structure at positions 3,6. In the sulfonic acid group, the sulfur atom is connected to three oxygen atoms, one of which is connected to the sulfur in the form of a double bond, and the other two oxygen atoms are connected to the hydrogen atom in the form of a hydroxyl group, and the sulfur atom is related to the 3,6 carbon atoms of the
In this way, the partial structures together constitute the chemical structure of 2% 2C7 -di-O- (benzyl carbonyl oxygen) -1% 2C8 -dinaphthyl methyl ether-3% 2C6 -disulfonic acid.
What are the main uses of 2,7 -di-O- (arsophenylazo) -1,8 -dihydroxynaphthalene-3,6 -disulfonic acid
2% 2C7-di-O- (benzyl carbonyl oxide) - 1% 2C8-dinaphthyl methyl ether-3% 2C6-disulfonic acid, its use is quite extensive.
In the field of organic synthesis, this compound is often used as a key intermediate. Due to its unique structure, it has the backbone of dinaphthyl methyl ether and is supplemented by specific substituents at both ends, so it can be derived through various chemical reactions. Many organic compounds with unique properties and functions can be derived. For example, when building complex organic molecular structures, with its specific functional groups, precise molecular splicing can be achieved, laying the foundation for the synthesis of new drugs, functional materials, etc.
In the field of medicinal chemistry, it may exhibit potential biological activity. The structure of the dinaphthyl group endows the molecule with certain rigidity and planarity, which is conducive to the interaction with biological macromolecules, such as proteins and nucleic acids. The introduction of sulfonic acid groups can improve the water solubility of compounds and enhance their transport and metabolism in vivo. The benzyl carbonyl oxygen moiety may participate in specific receptor-ligand interactions, which is expected to be developed into new therapeutic drugs, which can be effective for specific disease targets.
In the field of materials science, this compound also has great application prospects. Sulfonic acid groups can endow materials with ion exchange capabilities, and play a role in the preparation of ion exchange resins, proton conduction membranes, etc. The optical properties brought by the structure of dinaphthyl methyl ether may make the material useful in the fields of optoelectronic devices, such as organic Light Emitting Diode (OLED), light sensors, etc. By fine-tuning its structure, the optical properties of the material can be adjusted to meet different application needs.
In summary, 2% 2C7 -di-O - (benzyl carbonyl oxide) - 1% 2C8 -dinaphthyl methyl ether - 3% 2C6 -disulfonic acid has important potential application value in organic synthesis, drug development and material preparation, and is an organic compound worthy of further investigation.
What are the precautions for the use of 2,7-di-O- (arsophenylazo) -1,8-dihydroxynaphthalene-3,6-disulfonic acid?
2% 2C7-di-O- (benzyl carbonyloxy) - 1% 2C8-dinaphthyl methyl ether-3% 2C6-disulfonic acid, when it is in use, many should be avoided and must not be ignored.
First, the properties of this substance need to be detailed. It has a specific chemical structure and physical and chemical characteristics, and may have different performances under different environmental conditions. In case of temperature change or moisture change, its stability or change, when using it, pay attention to the environmental factors such as temperature and humidity, and ensure that it is in a suitable state to ensure its performance.
Second, the method of use must follow the specifications. When weighing, the accuracy is crucial, the difference in the slightest, or the reaction is biased. If the amount is too large, the reaction will be too large, and if the amount is too small, it will be difficult to achieve the expected effect. And its solubility in different solvents is different. The solvent must be carefully selected so that it can be evenly dispersed and fully reacted before it can be used to its fullest potential.
Third, the conditions of the reaction need to be precisely controlled. Temperature, pH, etc. are all key. If the temperature is too high, it may cause side reactions to occur, which will damage the purity of the product; if the temperature is too low, the reaction will be slow and time-consuming. The same is true for pH. Improper acid-base environment, or reaction process, or poor quality of the product.
Fourth, safety is the top priority. This substance may be toxic, corrosive and other hazards. When operating, protective gear must be complete, such as protective clothing, protective gloves and goggles, etc., must not be neglected. And its storage should also be properly kept away from fire and heat sources, and placed in a cool and dry place to prevent accidents.
Use 2% 2C7 - di-O - (benzyl carbonyl oxy) - 1% 2C8 - dinaphthyl methyl ether - 3% 2C6 - disulfonic acid, and handle it with care and care in all details to achieve the intended purpose and ensure safety.
How is the stability of 2,7 -di-O- (arsophenylazo) -1,8 -dihydroxynaphthalene-3,6 -disulfonic acid?
The stability of 2% 2C7-di-O- (benzyl carbonyl oxygen) - 1% 2C8-dinaphthyl methyl ether - 3% 2C6-disulfonic acid is discussed in detail.
In this compound, the substituent at 2,7 positions, that is, di-O- (benzyl carbonyl oxygen), benzyl carbonyl oxygen structure, the benzyl moiety has a certain steric resistance, and the conjugate system of the benzene ring can disperse the electron cloud and enhance the molecular stability. It is connected to the naphthalene ring and further stabilizes the molecular structure through π-π conjugation.
1,8-dinaphthyl methyl ether part, the fused ring structure of the naphthalene ring itself is quite stable, the methyl ether group is connected to the 1,8 position of the naphthalene ring, and the solitary pair electrons of the oxygen atom in the methoxy group can be conjugated with the naphthalene ring, so that the electron cloud distribution is more uniform, thereby improving the stability.
Furthermore, the introduction of 3,6-disulfonic acid group, the sulfonic acid group is a strong hydrophilic group, although it is an electron-absorbing group, but in the aqueous environment, the sulfonic acid group can interact with water molecules by forming hydrogen bonds, etc., so that the compound can form a stable dispersion system in water. At the same time, the negative charge of the sulfonic acid group can be dispersed through the conjugate system, so that the overall charge distribution
However, external factors also affect its stability. When the temperature increases, the thermal motion of the molecule intensifies, which may cause the vibration of the chemical bond to increase, and there is a risk of fracture, which may reduce the stability. Under light, if the photon energy is sufficient to stimulate the electron transition in the molecule, it may trigger photochemical reactions, change the molecular structure, and affect the stability. In an acid-base environment, sulfonic acid groups can undergo reactions such as ionization, and parts such as benzyl carbonyl oxygen may also be hydrolyzed due to acid-base action, which may destroy the original structure of the molecule and damage the stability.
In summary, the stability of 2% 2C7-di-O- (benzyl carbonyl oxygen) -1% 2C8-dinaphthyl methyl ether-3% 2C6-disulfonic acid is not only based on factors such as conjugation, steric resistance and charge distribution of its own structure, but also affected by external temperature, light, acid and base conditions.
What is the preparation method of 2,7 -di-O- (arsophenylazo) -1,8 -dihydroxynaphthalene-3,6 -disulfonic acid
To prepare 2,7-di-O- (benzyl carbonyl) -1,8-dinaphthyl methyl ether-3,6-disulfonic acid, the following ancient method can be used.
First take an appropriate amount of 1,8-dinaphthyl methyl ether and place it in a clean reactor. Dissolve it in an organic solvent such as dichloromethane to disperse it uniformly. In this solution, slowly add benzyl chloride and an appropriate amount of base, such as potassium carbonate. The effect of the base is to promote the reaction of benzyl with the hydroxyl group in 1,8-dinaphthyl methyl ether to form 2,7-di-O- (benzyl carbonyl) -1,8-dinaphthyl methyl ether. During the reaction, the temperature should be controlled in a moderate range and stirred continuously to facilitate the uniform progress of the reaction.
After the above reaction is completed, the reaction solution is properly handled and the product containing 2,7-di-O- (benzyl carbonyl) -1,8-dinaphthyl methyl ether is separated. Subsequently, the product is moved to another reaction vessel and concentrated sulfuric acid is added. Concentrated sulfuric acid is used here as a sulfonating agent. It reacts with 2,7-di-O- (benzylcarbonyl) -1,8-dinaphthyl methyl ether, and introduces a sulfonic acid group at its 3,6-position to obtain 2,7-di-O- (benzylcarbonyl) -1,8-dinaphthyl methyl ether-3,6-disulfonic acid. In this step, the control of temperature is crucial. If it is too high, side reactions will easily occur, and if it is too low, the reaction rate will be delayed.
After the reaction is completed, the reaction mixture is poured into ice water to stop the reaction. After that, the product can be purified by means of filtration, washing, etc. First wash with an appropriate amount of water to remove excess acid and water-soluble impurities, and then recrystallize with organic solvents such as ethanol to obtain pure 2,7-di-O- (benzyl carbonyl) -1,8-dinaphthyl methyl ether-3,6-disulfonic acid. The whole process should pay attention to the specifications of operation to ensure the safety and efficiency of the reaction.