What is the chemical structure of 4- ((4- (4-Hydroxy-2-Methylphenyl) Azo) Phenyl) Amino) -3-Nitrobenzenesulfonic Acid, Sodium Salt
This is the sodium salt of 4- {[4- (4-hydroxy-2-methylphenyl) azo] phenyl} amino-3-nitrobenzene sulfonic acid, and its chemical structure is quite complex.
And looking at this structure, first look at the main structure, which is built on the basis of benzene ring. The first benzene sulfonic acid base, which adheres to the sulfonic acid group on the benzene ring, is easy to dissociate hydrogen ions, so it is acidic, and the sodium salt form increases its water solubility. At this interposition of the benzene ring, nitro groups are added, and the presence of nitro groups changes the electron cloud density of the benzene ring, which has a great impact on the chemical properties of the compound, such as enhancing its oxidation.
Looking at the connected part, the amino group bridges another benzene ring, and the activity of this amino group cannot be ignored, and it can participate in a variety of chemical reactions. On the second benzene ring, the azo group is connected to the 4-hydroxy-2-methylphenyl group. As a chromogenic group, the azo group often imparts a specific color to the compound, and is widely used in dyes and other fields. In the 4-hydroxy-2-methylphenyl group, the hydroxy group can form a hydrogen bond, which affects the intermolecular force, while the methyl group changes the electron cloud distribution of the benzene ring, which in turn affects the physical and chemical properties of the compound.
The interaction of various parts in the overall structure of this compound jointly determines its unique chemical properties and application areas. It may have important uses in dyes, chemicals and other fields.
What are the main uses of 4- (((4-Hydroxy-2-Methylphenyl) Azo) Phenyl) Amino) -3-Nitrobenzenesulfonic Acid, Sodium Salt
The sodium salt of amino-3-nitrobenzenesulfonic acid. The main uses of this substance are as follows.
First, in the dye industry, it is often used as a key raw material for dye synthesis. By means of delicate chemical synthesis, it can be converted into colorful dyes, which are widely used in the field of fabric printing and dyeing. Due to the good affinity of the dye made of the sodium salt to the fabric, the fabric is dyed with bright color and good fastness. All kinds of natural fiber fabrics such as cotton, linen, silk, etc., after dyeing, not only the color is eye-catching, but also after many washes and light, it is still not easy to fade, which greatly improves the aesthetics and durability of the fabric.
Second, it also plays an important role in the ink manufacturing industry. It can be used as an ink colorant to give the ink excellent color performance. The inks prepared with it are printed on paper and other materials, with clear and full colors. They are widely used in book printing, packaging printing and other fields to ensure the high quality of the printed matter and attract the attention of consumers.
Third, it also plays a unique role in some analysis and testing scenes. Due to its structural properties, it can undergo exclusive chemical reactions with specific substances, resulting in significant color changes, so it can serve as an indicator in chemical analysis. In some acid-base titration, metal ion detection and other experiments and actual production quality control links, color changes are used to keenly indicate the end point of the reaction or the presence or absence of specific substances, helping to accurately analyze and detect.
Fourth, in terms of scientific research and exploration, as a special structural organic compound, it is a research object in many scientific research fields such as organic synthetic chemistry and materials science. By exploring its structural modification and properties, researchers are committed to developing materials with novel properties, such as new optoelectronic materials, which provide basic support for technological innovation and development in related fields.
What are the physical properties of 4- ((4- (4-Hydroxy-2-Methylphenyl) Azo) Phenyl) Amino) -3-Nitrobenzenesulfonic Acid, Sodium Salt
This compound is called the sodium salt of 4- {[4- ((4-hydroxy-2-methylphenyl) azo) phenyl] amino} -3 -nitrobenzene sulfonate. The following are its physical properties:
1. ** Appearance **: Sodium salts are mostly in solid form. Due to the molecular structure containing benzene ring, sulfonic acid group and azo group, etc., it is speculated that they may be in powder form, with a certain color or color due to conjugation system, or yellow to orange powder. The azo structure often gives the compound a color, and the molecule has a high degree of conjugation, which is easy to absorb visible light and develop color.
2. ** Solubility **: Contains sodium sulfonate salt, sodium sulfonate salt has strong hydrophilicity, making it easily soluble in water and can form a stable and uniform solution. Because the molecule contains hydrophobic groups such as benzene ring, it has limited solubility in organic solvents. It has low solubility in common organic solvents such as ethanol and ether, but may be slightly soluble in more polar organic solvents such as dimethyl sulfoxide (DMSO). Because DMSO can form a certain interaction with the compound and help it dissolve.
3. ** Melting point and boiling point **: The melting point and boiling point of organic compounds are related to their intermolecular forces. There are hydrogen bonds and van der Waals forces between the molecules of this compound. The ionic bonds between the sodium sulfonate salts are strong, which makes the intermolecular bonds tight, and the melting point is expected to be higher. However, due to the complex structure, it may decompose first when heated, and it is difficult to measure the clear boiling point. During the thermal decomposition process, chemical bonds break down to cause structural changes, or produce small molecule decomposition products.
4. ** Density **: The density is related to the compactness of the molecular structure and the relative molecular mass. This compound has a relatively large molecular weight. The structure contains multiple benzene rings and various functional groups. The molecular arrangement is relatively tight. It is estimated that its density is larger than that of water. The specific value needs to be accurately determined by experiments.
5. ** Stability **: Contains azo structure, which is not good for light and thermal stability. Under light, azo bonds are prone to cis-trans isomerization or photolysis, resulting in structural changes and color changes; when heated, nitro, azo bonds and other functional groups may decompose or undergo other chemical reactions, which affect stability. Storage requires protection from light and low temperature environments.
What is the synthesis method of 4- ((4- (4-Hydroxy-2-Methylphenyl) Azo) Phenyl) Amino) -3-Nitrobenzenesulfonic Acid, Sodium Salt
The sodium salt of 4 - {[4- ((4-hydroxy-2-methylphenyl) azo) phenyl] amino} -3 -nitrobenzene sulfonic acid, which is synthesized according to the ancient rules, is obtained by multi-step reaction.
The first step is to take 4-hydroxy-2-methylaniline, and carry out the diazotization reaction with appropriate reagents and conditions. The process of diazotization requires fine temperature control to ensure that the reaction is smooth and the product is pure. The resulting diazo salt is active in nature and is a key intermediate for subsequent reactions.
Next, take the benzene derivative containing amino group and couple it with the above diazonium salt. This step requires adjusting the appropriate pH value, so that the reaction can efficiently generate 4- ((4-hydroxy-2-methylphenyl) azo) aniline compounds under mild conditions. This product is separated and purified to obtain a purified intermediate.
Next, use a nitrogenation reagent to carry out a nitrogenation reaction on this intermediate. In the reaction system, a suitable solvent and catalyst are selected to precisely introduce the nitro group into the target position to obtain 4- {[4- ((4-hydroxy-2-methylphenyl) azo) phenyl] amino} -3 -nitrobenzene compounds.
In the last step, the above products are sulfonated with a sulfonation reagent, and then basic substances such as sodium hydroxide are used to form salts to obtain the sodium salt of 4- {[4- ((4-hydroxy-2-methylphenyl) azo) phenyl] amino} -3 -nitrobenzene sulfonic acid. After each step of the reaction, it needs to be separated and purified by methods such as crystallization and column chromatography to maintain the purity of the product and achieve the purpose of synthesis.
Does 4- ((4- (4-Hydroxy-2-Methylphenyl) Azo) Phenyl) Amino) -3-Nitrobenzenesulfonic Acid, Sodium Salt have an environmental impact?
Let's take a look at this "4- {[4- (4-hydroxy-2-methylphenyl) azo] phenyl} amino-3-nitrobenzene sulfonic acid, sodium salt" to see if it has environmental effects. This compound contains azo structure and sulfonic acid group, nitro and other functional groups.
Under specific conditions, the azo structure may decompose to produce aromatic amines. Some aromatic amines are carcinogenic. If this compound decomposes such substances in the environment and spreads with water, soil, etc., it may be a disaster to the ecology. It migrates with water currents, or pollutes rivers, lakes and seas, causing aquatic organisms to suffer from it and affecting the balance of the food chain.
The sulfonic acid group makes the compound water-soluble, which may affect the water quality in the water body, change the chemical properties of the water body, and interfere with the normal physiological activities of aquatic organisms. The presence of nitro groups also increases its chemical activity, generating new pollutants in the environment or participating in complex chemical reactions.
Furthermore, the form of sodium salts in the environment may affect the salinity of the soil. If it enters the soil, or changes the physical and chemical properties of the soil, it affects the absorption of nutrients and moisture by plant roots, and hinders plant growth and development. From this perspective, this "4- {[4- (4-hydroxy-2-methylphenyl) azo] phenyl} amino-3-nitrobenzene sulfonic acid, sodium salt" is likely to have many adverse effects on the environment. During its production, use and disposal, care should be taken to prevent it from escaping into the environment to ensure ecological safety.