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What are the main uses of Aniline-2,4-Disulfonic Acid Thiophenol?
Aniline-2,4-disulfonic acid and phenylthiophenol, both of which are widely used.
Aniline-2,4-disulfonic acid is a key raw material in the dye industry. It can be converted into colorful dyes through specific chemical processes and used in fabric printing and dyeing and other fields to make fabrics show colorful colors. In the field of pharmaceutical synthesis, it also plays an important role. As an intermediate, it participates in many drug synthesis reactions and helps to develop a variety of specific drugs.
Phenylthiophenol plays a significant role in organic synthesis. First, it is often used as a nucleophilic reagent to participate in various nucleophilic substitution reactions and form new carbon-sulfur bonds to synthesize complex organic compounds. Second, in the field of materials science, it can be used to prepare polymer materials with specific properties, such as some materials with special optical and electrical properties. In addition, in the fragrance industry, thiophenol can be chemically modified to synthesize flavorful fragrance components, adding uniqueness to the aroma.
These two play an indispensable role in many branches of chemical industry by virtue of their unique chemical properties, promoting industrial development and technological innovation.
What are the physical properties of Aniline-2,4-Disulfonic Acid Thiophenol?
The physical properties of aniline-2,4-disulfonic acid and thiophenol are particularly important in the academic community. Aniline-2,4-disulfonic acid is mostly solid at room temperature, white or near-white in color, and has a certain crystalline form. Its solubility is considerable in water. Because the sulfonic acid group is hydrophilic, it can strongly interact with water molecules. In organic solvents, the solubility varies depending on the type of solvent, but it is generally limited. From the melting point, due to the hydrogen bonds between molecules and the interaction between sulfonic acid groups, the melting point is quite high, and it requires considerable energy to cause it to melt.
As for thiophenol, the normal state is a foul-smelling liquid. This smell is strong and unique, resulting from the structure of sulfur atoms. Its boiling point is slightly lower than that of phenol, because the sulfur-hydrogen bond energy is weaker than that of the oxygen-hydrogen bond, and the intermolecular force is slightly inferior. Thiophenol has very little solubility in water, because its hydrophobic phenyl ring dominates, but it has good solubility in organic solvents such as ethanol and ether. Due to the principle of similar miscibility, thiophenol and organic solvents have similar molecular structures and are miscible. Its density is slightly higher than that of water, and it will settle in water. The physical properties of the two have their own characteristics. When applied in the fields of chemical industry and scientific research, these physical properties are the key basis for the selection of operation and reaction conditions.
What are the chemical properties of Aniline-2,4-Disulfonic Acid Thiophenol?
Aniline-2,4-disulfonic acid and thiophenol are both organic compounds with unique chemical properties and great significance in the field of organic synthesis.
Aniline-2,4-disulfonic acid, acidic, because its sulfonic acid group can ionize hydrogen ions. This property allows it to react with bases to form corresponding salts. For example, when reacted with sodium hydroxide, aniline-2,4-disulfonic acid can be formed. This reaction is typical of acid-base neutralization, in which the acidic nature of the sulfonic acid group is fully demonstrated. At the same time, its phenyl ring structure gives it the activity of electrophilic substitution reaction. Because the sulfonic acid group is an meta-site group, electrophilic reagents tend to attack the meta-site of the benzene ring. For example, under appropriate conditions, nitrification reactions can occur with mixed acids of nitric acid and sulfuric acid, and nitro groups are introduced into the benzene ring interposition. This reaction provides a path for the construction of nitro-containing compounds in organic synthesis.
Sulfenol, which contains a sulfhydryl group (-SH) in the molecule, which makes it have special chemical properties. The sulfur atom of the sulfenyl group has a lone pair electron, which is nucleophilic and can participate in nucleophilic substitution reactions. For example, it can react with halogenated hydrocarbons. The sulfur atom attacks the carbon atom of the halogenated hydrocarbon, and the halogen atom leaves to form thioether compounds. This reaction is widely used in the synthesis of organic sulfur compounds. Moreover, thiophenol has strong reducing properties, and the sulfur in the mercapto group is in a Under the action of mild oxidants, it can be oxidized to disulfide. For example, in air, thiophenol can be oxidized slowly, and the two thiol groups dehydrogenate to form disulfide bonds to form diphenylene disulfide. In addition, thiophenol is slightly more acidic than phenol. Because the radius of sulfur atoms is larger than that of oxygen atoms, it has a weaker binding force on hydrogen atoms, and hydrogen atoms are more likely to ionize. This property also affects its performance in chemical reactions.
What is the production method of Aniline-2,4-Disulfonic Acid Thiophenol?
The method of making aniline-2,4-disulfonic acid begins with aniline and coheats with sulfuric acid. Temperature control and timing are necessary, and the temperature is suitable for a long time to make the sulfonation process, and aniline-2,4-disulfonic acid is obtained.
As for the method of making thiophenol, in the past, there was a method of co-reacting benzenesulfonyl chloride with zinc powder and acid. Take benzenesulfonyl chloride first, mix it with zinc powder, and add acid to promote the reaction. Zinc powder is used as a return agent to break the bond of sulfur chloride in benzenesulfonyl chloride, and the chlorine is exchanged for hydrogen to form thiophenol. There is also a method of reacting halogenated benzene with In halogenated benzene, the halogen atom has good activity. In case of sulfur hydride alkali, the halogen atom is replaced by sulfur hydrogen radical, and thiophenol is produced.
When operating, all should be handled with caution. If sulfuric acid is used to prevent its corrosion; zinc powder is used to avoid the risk of fire and explosion. And in the back, the impurities are removed and purified to obtain pure products.
However, the ancient method may have the disadvantages of being difficult and polluted. Today's chemical technology is advanced, or there is a new way, and researchers often seek better methods, with high efficiency and less pollution, which should meet the needs of today's industry.
What are the precautions for the storage and transportation of Aniline-2,4-Disulfonic Acid Thiophenol?
Aniline-2,4-disulfonic acid and thiophenol need to pay attention to many matters during storage and transportation.
First, both are chemically active and should be properly stored in a cool, dry and well-ventilated place. Avoid direct sunlight, because light may cause chemical reactions and cause changes in their properties. Such as aniline-2,4-disulfonic acid, light may accelerate its decomposition and affect quality.
Second, storage temperature is crucial. Excessive temperature may enhance the reactivity of the two, or cause unexpected reactions. Aniline-2,4-disulfonic acid may react with components in the air at high temperatures, and thiophenol becomes more volatile at high temperatures, which not only loses materials, but also poses safety hazards.
Third, the two should be stored separately from oxidants, acids, bases and other substances. Aniline-2,4-disulfonic acid is acidic and prone to neutralization in case of alkali; thiophenol contains sulfur functional groups and is easily oxidized in case of oxidants, which will affect its original properties.
Fourth, ensure that the packaging is complete and sealed during transportation. If the packaging is damaged, aniline-2,4-disulfonic acid or deliquescence, thiophenol or volatile leakage will pollute the environment and endanger the safety of transporters.
Fifth, the means of transportation should be clean and dry to avoid residual substances from reacting with it. And to prevent bumps and collisions during transportation to prevent packaging damage.
Sixth, operators need to be professionally trained and familiar with the characteristics of both and emergency treatment methods. In the event of leakage and other situations, effective measures can be taken quickly to reduce hazards.